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Type: Artigo de periódico
Title: Ionic Liquids and the Heck Coupling Reaction: An Update
Author: Prediger, P
Genisson, Y
Correia, CRD
Abstract: In this review update we provide a critical analysis of recent results concerning the use of ionic liquids (ILs) as viable, effective, and environmental friendly media for the Heck reactions (HR). The examples selected illustrate the multifaceted action of ILs as nanoparticles stabilizers, promoters of ligand-assisted HR, promoters of phosphine-free HR, solvent for the Heck-Matsuda reactions employing arenediazonium salts, in the dehydrative Heck olefination, and as charged-tagged pre-catalysts. These selected reports aim at demonstrating the scope and the impact of Ils on new discoveries, as well as to illustrate the new opportunities and challenges they offer for those interested in catalysis and organic synthesis in general.
Subject: Ionic liquids
Heck reaction
N-heterocyclic carbenes
Country: Emirados Árabes Unidos
Editor: Bentham Science Publ Ltd
Citation: Current Organic Chemistry. Bentham Science Publ Ltd, v. 17, n. 3, n. 238, n. 256, 2013.
Rights: fechado
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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