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|Type:||Artigo de periódico|
|Title:||Diastereoselective Approach to Substituted Oxazolidinones from Morita-Baylis-Hillman Adducts|
|Abstract:||We disclose herein a new strategy for the diastereoselective preparation of 4- and 4,5-substituted oxazolidinones from Morita-Baylis-Hillman adducts. The strategy is based on an intramolecular cyclization involving a nucleophilic attack of an alkoxide ion to the carbonyl group of a carbamate. The latter is prepared from a Curtius rearrangement having Morita-Baylis-Hillman adduct as substrate. The oxazolidinones were prepared in six steps with an overall yield of 18% and 49%.|
|Editor:||Taylor & Francis Inc|
|Citation:||Synthetic Communications. Taylor & Francis Inc, v. 41, n. 2, n. 227, n. 242, 2011.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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