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Type: Artigo de periódico
Title: Diastereoselective epoxidation of allylic diols derived from Baylis-Hillman adducts
Author: Porto, RS
Vasconcellos, MLAA
Ventura, E
Coelho, F
Abstract: The results of a highly diastereoselective epoxidation of allylic diols derived from Baylis-Hillman adducts are reported. The formation of an intramolecular hydrogen bond seems to be responsible for the high anti diastereoselection obtained in this epoxidation reaction. The results are complementary to those obtained in the direct epoxidation of Baylis-Hillman adducts, in which an elevated syn diastereoselectivity was observed.
Subject: Baylis-Hillman reaction
allylic alcohol
Country: Alemanha
Editor: Georg Thieme Verlag Kg
Citation: Synthesis-stuttgart. Georg Thieme Verlag Kg, n. 14, n. 2297, n. 2306, 2005.
Rights: aberto
Identifier DOI: 10.1055/s-2005-872091
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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