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Type: Artigo de periódico
Title: Dba-free palladium intermediates of the Heck-Matsuda reaction
Author: Machado, AHL
Milagre, HMS
Eberlin, LS
Sabino, AA
Correia, CRD
Eberlin, MN
Abstract: The 'dba-free' Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(II) during a Wacker type reaction and several 'dba-free' arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested.
Country: Inglaterra
Editor: Royal Soc Chemistry
Citation: Organic & Biomolecular Chemistry. Royal Soc Chemistry, v. 11, n. 20, n. 3277, n. 3281, 2013.
Rights: embargo
Identifier DOI: 10.1039/c3ob40142a
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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